Safe and Inexpensive Hydrogen Production as a Future Energy Source

Hydrogen gas can be produced efficiently from organosilanes, some of which are suitably air-stable, non-toxic, and cheap. Catalysts that can efficiently produce hydrogen from organosilanes are therefore desired with the ultimate goal of realizing safe, inexpensive hydrogen production in high yield. Ideally, the catalyst should also operate at room temperature under aerobic conditions without the need for additional energy input.

 

Figure: a) Gold nanoparticle catalyst (Au/HAP-NC), b) Images of gold nanoparticles (black dot in red circle) through Transmission Electron Microscope, c) Annular Dark Field of gold nanoparticles through Scanning Electron Microscope  

Credit: Osaka University

A research team led by Kiyotomi Kaneda and Takato Mitsudome at Osaka University have now developed a catalyst that realizes efficient environmentally friendly hydrogen production from organosilanes. The catalyst is composed of gold nanoparticles with a diameter of around 2 nm supported on hydroxyapatite. The catalyst was synthesized from chloroauric acid using glutathione as a capping agent to prevent nanoparticle aggregation, resulting the formation of small size of gold nanoparticles. Glutathione-capped gold nanoparticles were then adsorbed on hydroxyapatite and glutathione was removed by subsequent calcination.

The team then added the nanoparticle catalyst to solutions of different organosilanes to measure its ability to induce hydrogen production. The nanoparticle catalyst displayed the highest turnover frequency and number attained to date for hydrogen production catalysts from organosilanes. For example, the nanoparticle catalyst converted 99% of dimethylphenylsilane to the corresponding silanol in just 9 min at room temperature, releasing an equimolar amount of hydrogen gas at the same time. Importantly, the catalyst was recyclable without loss of activity. On/off switching of hydrogen production was achieved using the nanoparticle catalyst because it could be easily separated from its organosilane substrate by filtration. The activity of the catalyst increased as the nanoparticle size decreased.

A prototype portable hydrogen fuel cell containing the nanoparticle catalyst and an organosilane substrate was fabricated. The fuel cell generated power in air at room temperature and could be switched on and off as desired. Images of the catalyst after use in the fuel cell resembled those of the unused catalyst, indicating that the hydroxyapatite-supported nanoparticle catalyst readily resisted aggregation.

Generation of hydrogen from inexpensive organosilane substrates under ambient conditions without additional energy input represents an exciting advance towards the goal of using hydrogen as a green energy source.

Contacts and sources:

Osaka University

Citation：“On-demand Hydrogen Production from Organosilanes at Ambient Temperature Using Heterogeneous Gold Catalysts” Authors: Takato Mitsudome, Teppei Urayama, Taizo Kiyohiro, Zen Maeno, Tomoo Mizugaki, Koichiro Jitsukawa and Kiyotomi Kaneda  Journal: Scientific Reports
DOI: 10.1038/srep37682 http://www.nature.com/articles/srep37682