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New Solar Device Makes Fuel From CO2

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University of Cambridge researchers have developed a standalone device that converts sunlight, carbon dioxide and water into a carbon-neutral fuel, without requiring any additional components or electricity.

The device, developed by a team from the University of Cambridge, in collaboration with the team of Professor Kazunari Domen from the University of Tokyo, a co-author of the study, is a significant step toward achieving artificial photosynthesis – a process mimicking the ability of plants to convert sunlight into energy. It is based on an advanced ‘photosheet’ technology and converts sunlight, carbon dioxide and water into oxygen and formic acid – a storable fuel that can be either be used directly or be converted into hydrogen.

Image Credit: University of Cambridge. Click image for the largest view.

The results, reported with a paper published in the journal Nature Energy, represent a new method for the conversion of carbon dioxide into clean fuels. The wireless device could be scaled up and used on energy ‘farms’ similar to solar farms, producing clean fuel using sunlight and water.

Harvesting solar energy to convert carbon dioxide into fuel is a promising way to reduce carbon emissions and transition away from fossil fuels. However, it is challenging to produce these clean fuels without unwanted by-products.

First author Dr Qian Wang from Cambridge’s Department of Chemistry said, “It’s been difficult to achieve artificial photosynthesis with a high degree of selectivity, so that you’re converting as much of the sunlight as possible into the fuel you want, rather than be left with a lot of waste.”

Professor Erwin Reisner, the paper’s senior author said, “In addition, storage of gaseous fuels and separation of by-products can be complicated. We want to get to the point where we can cleanly produce a liquid fuel that can also be easily stored and transported.”

In 2019, researchers from Reisner’s group developed a solar reactor based on an ‘artificial leaf’ design, which also uses sunlight, carbon dioxide and water to produce a fuel, known as syngas. The new technology looks and behaves quite similarly to the artificial leaf but works in a different way and produces formic acid.

While the artificial leaf used components from solar cells, the new device doesn’t require these components and relies solely on photocatalysts embedded on a sheet to produce a so-called photocatalyst sheet. The sheets are made up of semiconductor powders, which can be prepared in large quantities easily and cost-effectively.

In addition, this new technology is more robust and produces clean fuel that is easier to store and shows potential for producing fuel products at scale. The test unit is 20 square centimeters in size, but the researchers say that it should be relatively straightforward to scale it up to several square meters. In addition, the formic acid can be accumulated in solution, and be chemically converted into different types of fuel.

“We were surprised how well it worked in terms of its selectivity – it produced almost no by-products,” said Wang. “Sometimes things don’t work as well as you expected, but this was a rare case where it actually worked better.”

The carbon-dioxide converting cobalt-based catalyst is easy to make and relatively stable. While this technology will be easier to scale up than the artificial leaf, the efficiencies still need to be improved before any commercial deployment can be considered. The researchers are experimenting with a range of different catalysts to improve both stability and efficiency.

The researchers are now working to further optimize the system and improve efficiency. Additionally, they are exploring other catalysts for using on the device to get different solar fuels.

Reisner noted, “We hope this technology will pave the way toward sustainable and practical solar fuel production.”

There have been quite a few of these solar driven recycling CO2 back to fuel ideas make progress. This one looks especially promising. Its worth noting that we still are not seeing costs of them or the area needed for solar irradiation to get to economic scale.

Perhaps we’re getting closer to that kind of information. With that data included we might get from very interesting to hopeful.

The post New Solar Device Makes Fuel From CO2 first appeared on New Energy and Fuel.



Source: https://newenergyandfuel.com/http:/newenergyandfuel/com/2020/09/17/new-solar-device-makes-fuel-from-co2/


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