How Gold Melts at Room Temperature

Ludvig de Knoop, from Chalmers’ Department of Physics, placed a small piece of gold in an electron microscope. Observing it at the highest level of magnification and increasing the electric field step-by-step to extremely high levels, he was interested to see how it influenced the gold atoms.

It was when he studied the atoms in the recordings from the microscope, that he saw something exciting. The surface layers of gold had actually melted – at room temperature.

“I was really stunned by the discovery. This is an extraordinary phenomenon, and it gives us new, foundational knowledge of gold,” says Ludvig de Knoop.

What happened was that the gold atoms became excited. Under the influence of the electric field, they suddenly lost their ordered structure and released almost all their connections to each other. Upon further experimentation, the researchers discovered that it was also possible to switch between a solid and a molten structure.

The discovery of how gold atoms can lose their structure in this way is not just spectacular, but also groundbreaking scientifically. Together with the theoretician Mikael Juhani Kuisma, from the University of Jyväskylä in Finland, Ludvig de Knoop and colleagues have opened up new avenues in materials science. The results are now published in the journal Physical Review Materials.

The illustration shows the atoms of a gold cone exposed to a strong electric field. We also see the field (around the tip of the cone) that excites the gold atoms. They break almost all their connections to each other and the surface layers begin to melt.

Credit: Alexander Ericson