Has Earth’s Oxygen Rusted The Moon For Billions Of Years?

To the surprise of many planetary scientists, the oxidized iron mineral hematite has been discovered at high latitudes on the Moon. That’s according to a study published in Science Advances led by Shuai Li, an assistant researcher at the Hawaiʻi Institute of Geophysics and Planetology (HIGP) in the University of Hawaiʻi at Mānoa School of Ocean and Earth Science and Technology (SOEST).

Iron is highly reactive with oxygen—forming reddish rust commonly seen on Earth. The lunar surface and interior, however, are virtually devoid of oxygen, so pristine metallic iron is prevalent on the Moon, and highly oxidized iron has not been confirmed in samples returned from the Apollo missions. In addition, hydrogen in solar wind blasts the lunar surface, which acts in opposition to oxidation. Thus, the presence of highly oxidized iron-bearing minerals, such as hematite, on the Moon is an unexpected discovery.

“Our hypothesis is that lunar hematite is formed through oxidation of lunar surface iron by the oxygen from the Earth’s upper atmosphere that has been continuously blown to the lunar surface by solar wind when the Moon is in Earth’s magnetotail during the past several billion years,” said Li.

To make the discovery, Li, HIGP professor Paul Lucey and co-authors from NASA’s Jet Propulsion Laboratory (JPL) and elsewhere analyzed the hyperspectral reflectance data acquired by the Moon Mineralogy Mapper (M3) designed by NASA JPL onboard India’s Chandrayaan-1 mission.

This new research was inspired by Li’s previous discovery of water ice in the Moon’s polar regions in 2018.

“When I examined the M3 data at the polar regions, I found some spectral features and patterns are different from those we see at the lower latitudes or the Apollo samples,” said Li. “I was curious whether it is possible that there are water-rock reactions on the Moon. After months of investigation, I figured out I was seeing the signature of hematite.”

The team found that the locations where hematite is present are strongly correlated with water content at high latitude Li and others found previously and are more concentrated on the nearside, which always faces the Earth.

“This discovery will reshape our knowledge about the Moon’s polar regions,” said Li. “Earth may have played an important role on the evolution of the Moon’s surface.”

For more see SOEST’s website.

Contacts and sources:

Publication: Widespread hematite at high latitudes of the Moon.
Shuai Li, Paul G. Lucey, Abigail A. Fraeman, Andrew R. Poppe, Vivian Z. Sun, Dana M. Hurley and Peter H. Schultz. Science Advances, 2020 DOI: 10.1126/sciadv.aba1940