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Controversy Clarified: Why Two Insulators Together Can Transport Electricity

Wednesday, July 4, 2012 10:56

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In 2004, researchers discovered something amazing: If the two materials, SrTiO3 and LaAlO3, both of which are electrical insulators, are joined together, a thin, electrically conducting region is formed at their interface. Over the subsequent three years, a number of hypotheses were proposed to explain this effect, which has led to controversy ever since.

Structure of the material investigated; Lower: Pure SrTiO3 (dark blue: strontium Sr; turquoise: titanium Ti; grey: oxygen O) with alternating planes of SrO and TiO2. Upper: Mixed layer of SrTiO3 and LaAlO3 (red: lanthanum La; orange: aluminium Al).

Credit:
Paul Scherrer Institut (PSI)

“There are conference sessions at which the majority of contributions are about this effect,” says Mathilde Reinle-Schmitt, a researcher at PSI and the first author of the work presented here. Of the various explanations forwarded, effectively only two competing hypotheses have survived. In order to compare their relative merits, an appropriate experiment was performed by scientists at PSI, together with colleagues from the University of Geneva. In addition, scientists from the University of Liège have contributed important theoretical insights.

Intermixing or polar catastrophe?

Both substances are complex metal-oxide materials – so-called perovskites – with a typical layered structure. In SrTiO3, the structure consists of alternating planes of strontium oxide (SrO) and titanium dioxide (TiO2), while in LaAlO3, they are lanthanum oxide (LaO) and aluminium dioxide (AlO2). The two materials, however, differ in one crucial aspect: In SrTiO3, both planes are electrically neutral, while in LaAlO3 they are alternately positively and negatively charged.

The combination of two such materials leads, in the opinion of one school of thought, to the transfer of mobile electrons to the interface between the two materials, thereby making this ultrathin interfacial region conducting. This happens, however, only when the LaAlO3 film is thick enough. Otherwise, the combination of materials remains an insulator. This hypothesis is known as the «polar catastrophe». Other researchers are nevertheless convinced that conductivity is created because both compounds are known to combine at their interface and this intermixed material is conducting.

The appropriate experiment

In order to clarify this controversy, the researchers wanted to answer the question, «Is a mixture of the two substances conducting?” Mathilde Reinle-Schmitt says, “We used again SrTiO3 as the substrate, but now, instead of depositing pure LaAlO3 on top of this, we used a mixture of SrTiO3 und LaAlO3 in various proportions and thicknesses and then measured the conductivity. The results were surprising. For thin layers of deposited mixtures, the system was insulating, while for thicker layers the interface was conducting, although the layers themselves were not, just as for pure LaAlO3. What changed was that the mixed layer had to be correspondingly thicker the less LaAlO3 there was in the mixture. This result agrees perfectly with the polar catastrophe hypothesis,” says Claudia Cancellieri, PSI scientist and second author of the article. “It would be very difficult to explain these results in terms of intermixing.”

Numerous applications in view

Perovskites, the category to which the materials being investigated belong, often have interesting electrical and magnetic properties, some of which have never been observed in any other materials. An additional important property is highlighted by Philip Willmott, leader of the investigating group at PSI,

The researchers Claudia Cancellieri (left) and Mathilde Reinle-Schmitt at an apparatus that produces thin layers of different materials with the aid of a laser

Credit: Paul Scherrer Institute/M. Fischer

“In contrast to traditional semiconductors used today, different perovskites have a similar crystalline and chemical structure and can thus be easily incorporated together, so that materials with different characteristics can be combined into a single device, such as a superconductor with a material which reacts sensitively to magnet fields, or one which can detect substances in the air.» Materials in which the current does not flow in all three dimensions, but in only one or, as here, in two, are also current topics of research that could lead to numerous applications.

Contacts and sources:
Paul Scherrer Institut (PSI)

Citation: Tunable conductivity threshold at polar oxide interfacesM.L. Reinle-Schmitt, C. Cancellieri, D. Li, D. Fontaine, M. Medarde, E. Pomjakushina, C.W. Schneider, S. Gariglio,
Ph. Ghosez, J.-M- Triscone, P.R. Willmott
Nature Communications:
DOI: 10.1038/ncomms1936

Source:

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