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Quasicrystals Discovery Wins Nobel Prize For Chemistry

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In quasicrystals, we find the fascinating mosaics of the Arabic world reproduced at the level of atoms: regular patterns that never repeat themselves. However, the configuration found in quasicrystals was considered impossible, and Daniel Shechtman had to fight a fierce battle against established science. The Nobel Prize in Chemistry 2011 has fundamentally altered how chemists conceive of solid matter.

 
 
Electron diffraction pattern from an icosahedral quasicrystal. Note the presence of perfect pentagons 
highlighted in the diagram to the right. The linear scale between pentagons is, and the scale between a pentagon inscribed in another pentagon is  . One of the great challenges of quasicrystal structure work is also apparent in this image. The intensity distribution of the diffraction pattern varies over many orders of magnitude, even in electron diffraction, and measuring the crucial weak reflections in an X-ray diffraction pattern within a reasonable time frame has only become possible with modern area detectors that were not around at the time of discovery.  

On the morning of 8 April 1982, an image counter to the laws of nature appeared in Daniel Shechtman’s electron microscope. In all solid matter, atoms were believed to be packed inside crystals in symmetrical patterns that were repeated periodically over and over again. For scientists, this repetition was required in order to obtain a crystal.

Shechtman’s image, however, showed that the atoms in his crystal were packed in a pattern that could not be repeated. Such a pattern was considered just as impossible as creating a football using only six-cornered polygons, when a sphere needs both five- and six-cornered polygons. His discovery was extremely controversial. In the course of defending his findings, he was asked to leave his research group. However, his battle eventually forced scientists to reconsider their conception of the very nature of matter.

Aperiodic mosaics, such as those found in the medieval Islamic mosaics of the Alhambra Palace in Spain and the Darb-i Imam Shrine in Iran, have helped scientists understand what quasicrystals look like at the atomic level. In those mosaics, as in quasicrystals, the patterns are regular – they follow mathematical rules – but they never repeat themselves.

 
Inside a crystal, atoms are ordered in repeating patterns, and depending on the chemical composition, they have different symmetries. In figure 3a, we see that each atom is surrounded by three identical atoms in a repeating pattern, yielding a threefold symmetry. Rotate the image 120 degrees and the same pattern will appear. The same principle applies to fourfold symmetries (figure 3b) and sixfold symmetries (figure 3c). The pattern  repeats itself and if you rotate the image, 90 degrees and 60 degrees, respectively, the same pattern appears

When scientists describe Shechtman’s quasicrystals, they use a concept that comes from mathematics and art: the golden ratio. This number had already caught the interest of mathematicians in Ancient Greece, as it often appeared in geometry. In quasicrystals, for instance, the ratio of various distances between atoms is related to the golden mean.

Following Shechtman’s discovery, scientists have produced other kinds of quasicrystals in the lab and discovered naturally occurring quasicrystals in mineral samples from a Russian river. A Swedish company has also found quasicrystals in a certain form of steel, where the crystals reinforce the material like armor. Scientists are currently experimenting with using quasicrystals in different products such as frying pans and diesel engines.

 Section perpendicular to the decagonal axis of Al-Co-N Quasicrystal


Contacts and sources:
Nobel Prize
Swedish Royal Society

 

Daniel Shechtman, Israeli citizen. Born 1941 in Tel Aviv, Israel. Ph.D. 1972 from Technion – Israel Institute of Technology, Haifa, Israel. Distinguished Professor, The Philip Tobias Chair, Technion – Israel Institute of Technology, Haifa, Israel.
http://materials.technion.ac.il/shechtman.html


Read more at Nano Patents and Innovations


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