Catching More Rays with Quantum Dots and Organic Molecules for More Solar Power

Organic molecules aid charge transfer from large lead sulfide quantum dots for improved solar cell performance.

Credit: © 2015 Wiley.

“One of the greatest advantages of quantum dots for solar cell technologies is their optical properties’ tunability,” explained KAUST Assistant Professor of Chemical Science Omar Mohammed. “They can be controlled by varying the size of the quantum dot.”

Mohammed and his colleagues are developing lead sulfide quantum dots for optical energy harvesting; these tend to be larger than dots made from other materials. Accordingly, lead sulfide quantum dots can absorb light over a wider range of frequencies. This means they can absorb a greater proportion of the light from the sun when compared to other smaller dots.

To make a fully functioning solar cell, electrons must be able to move away from the quantum dot absorption region and flow toward an electrode. Ironically, the property of large lead sulfide quantum dots that makes them useful for broadband absorption—a smaller electron energy bandgap—also hinders this energy harvesting process. Previously, efficient electron transfer had only been achieved for lead sulfide quantum dots smaller than 4.3 nanometers across, which caused a cut-off in the frequency of light converted.

The innovation by Mohammed and the team was to mix lead sulfide quantum dots of various sizes with molecules from a family known as porphyrins1. The researchers showed that by changing the porphyrin used, it is possible to control the charge transfer from large lead sulfide dots; while one molecule switched off charge transfer altogether, another one enabled transfer at a rate faster than 120 femtoseconds.

The team believe this improvement in energy harvesting ability is due to the interfacial electrostatic interactions between the negatively charged quantum dot surface and the positively charged porphyrin.

“With this approach, we can now extend the quantum dot size for efficient charge transfer to include most of the near-infrared spectral region, reaching beyond the previously reported cut-off,” stated Mohammed. “We hope next to implement this idea in solar-cells with different architectures to optimize efficiency.”

Contacts and sources:

King Abdullah University of Science and Technology

Citation: El-Ballouli, A. O., Alarousu, E., Kirmani, A. R., Amassian, A., Bakr, O. M. & Mohammed O. F. Overcoming the cut-off charge transfer bandgaps at the PbS quantum dot interface.Advanced Functional Materials 25, 7435–7441 (2015). | article