Seeking Cheap Hydrogen: Splitting Water for the Cost of a Nickel

Noble metals, such as iridium and ruthenium, have excellent oxygen-evolution performance, but are very expensive. As a cheaper alternative, Ph.D. student Tatsuya Shinagawa and Internship student Marcus Ng were guided by Associate Professor Kazuhiro Takanabe from the KAUST Catalysis Center to use a simple chemical method to improve the oxygen-evolution reaction.

Nickel-based electrocatalysts have shown encouraging performance in previous experiments. Notable amongst these is nickel-iron oxide; but the cost and complexity of its synthesis is a drawback.

“Existing electrolyzers function in extremely alkaline or acidic environments, and these harsh conditions will be costly when driven by renewable energy sources,” said Shinagawa. “Also important is that most studies on electrocatalytic water splitting have been performed at room temperature. Higher temperatures are required in practical systems.”

The team’s protocol involves repeated redox cycling of nickel in a carbonate or phosphate electrolyte at moderate pH and temperature of approximately 55°C and the evaluation of the water-splitting process performance at elevated temperatures (up to 80°C)

Imaging the resultant nickel electrode with a scanning electron microscope indicated that the fabrication process restructures the surface to create a layer of nickel-oxide hydroxide more than one-millimeter thick. The three-dimensional structure of this layer can trap weakly bound alkali-metal cations and water.

The team showed that their electrode exhibited greatly superior oxygen-evolution reaction performance compared to nickel-iron oxide under near neutral pH conditions and at temperatures commonly used in industrial processing.

“We hope to follow this study by building a further understanding of the material’s properties and its performance,” said Shinagawa. “For example, an in-depth study on kinetics will identify the limiting reaction step over the prepared nickel-based electrocatalyst, which will lead to further improvement of the catalytic activity.”

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Citation: Shinagawa, T., Ng, M. T.-K. & Takanabe, K. Boosting the performance of the nickel anode in the oxygen evolution reaction by simple electrochemical activation. Angewandte Chemie 56, 5061(2017). article