New Catalyst Recycles Carbon Dioxide

Oregon State University researchers have made a key advance in the green chemistry pursuit of converting the greenhouse gas carbon dioxide into reusable forms of carbon.

The research effort led by Zhenxing Feng of the OSU College of Engineering and colleagues at Southern University of Science and Technology in China and Stanford University describes a new type of electrocatalyst that uses electrochemical reduction. The research paper has been published in Nature Energy.

The catalyst can selectively promote a CO₂ reduction reaction resulting in a desired product – carbon monoxide was the choice in this research. A catalyst is anything that speeds the rate of a chemical reaction without being consumed by the reaction.

Feng, assistant professor of chemical engineering, explained, “The reduction of carbon dioxide is beneficial for a clean environment and sustainable development. In contrast to traditional CO₂ reduction that uses chemical methods at high temperatures with a high demand of extra energy, electrochemical CO₂ reduction reactions can be performed at room temperature using liquid solution. And the electricity required for electrochemical CO₂ reduction can be obtained from renewable energy sources such as solar power, thus enabling completely green processes.”

A reduction reaction means one of the atoms involved gains one or more electrons. In the electrochemical reduction of carbon dioxide, metal nanocatalysts have shown the potential to selectively reduce CO₂ to a particular carbon product. Controlling the nanostructure is critical for understanding the reaction mechanism and for optimizing the performance of the nanocatalyst in the pursuit of specific products, such as carbon monoxide, formic acid or methane, that are important for other chemical processes and products.

“However, due to many possible reaction pathways for different products, carbon dioxide reduction reactions have historically had low selectivity and efficiency,” Feng said. “The electrocatalysts need to promote the reaction with high selectivity to get one certain product, carbon monoxide in our case. Despite many efforts in this field, there had been little progress.”

Feng and his research co-leaders tried a new strategy. They made nickel phthalocyanine as a molecularly engineered electrocatalyst and found it showed superior efficiency at high current densities for converting CO₂ to carbon monoxide in a gas-diffusion electrode device, with stable operation for 40 hours.

“To understand the reaction mechanism of our catalyst, my group at OSU used X-ray absorption spectroscopy to monitor the catalyst’s change during the reaction processes, confirming the role of the catalyst in the reaction,” Feng said. “This collaborative work demonstrates a high-performance catalyst for green processes of electrochemical CO₂ reduction reactions. It also sheds light on the reaction mechanism of our catalyst, which can guide the future development of energy conversion devices as we work toward a negative-carbon economy.”

Maoyu Wang and Marcos Lucero of OSU were among the collaborators, who also included scientists from Yale University, Northwestern University and the Argonne National Laboratory.

Along with Feng, Yang-Gang Wang and Yongye Liang of the Southern University of Science and Technology are the study’s co-corresponding authors.

The National Science Foundation, the Department of Energy, the Guangdong Provincial Key Laboratory of Catalysis, Oregon State University, the National Natural Science Foundation of China and the Guangdong-Hong Kong-Macao Joint Laboratory for Photonic-Thermal-Electrical Energy Materials and Devices supported this research.

This is another in a list of research efforts showing progress for recycling CO₂. We’re sure to see more and its likely some of these will entice some commercial attention. Perhaps we will see the best of these get to commercial scale up someday. But for now, the processes have to be extremely low cost to implement and turn a profit in a very low price market. Its a good time to drive this research forward as it should be “economy ready” if it can progress in these circumstances.

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