New Catalyst Makes Carbon Fuels From CO2

University of Illinois at Urbana-Champaign scientists’ new catalyst produces hydrocarbons when CO₂ and water react with the light driven catalyst. The researchers reported that small quantities of useful molecules such as hydrocarbons are produced when carbon dioxide and water react in the presence of light and the new silver nanoparticle catalyst. Their validation study – made possible through the use of a high-resolution analytical technique – could open a new technology for CO₂-reduction technologies that allow industrial-scale production of renewable carbon-based fuels.

The research, led by University of Illinois Urbana-Champaign chemistry professor Prashant Jain, probed chemical activity at the surface of silver nanoparticle catalysts under visible light and used carbon isotopes to track the origin and production of these previously undetected chemical reactions.

The findings have been published in the journal Nature Communications.

The paper noted that recycling CO₂ by sunlight-driven conversion of CO₂ and water into energy-dense multicarbon compounds is a viable technology for renewable energy generation and chemical manufacturing. Because of this, researchers have been on the hunt for synthetic catalysts that facilitate large-scale CO₂ reduction into multicarbon molecules.

Professor Jain explained, “Industrial-level catalytic chemical reactions are usually tested and optimized on the basis of the bulk profile of the final products. But there are chemical species formed at the intermediate stages of such reactions, on the surface of the catalysts, that might be too scarce to detect and measure using conventional methods but are fundamental signifiers of how a catalyst functions.”

In the lab, Jain’s team used a specially outfitted Raman spectroscope to detect and identify single molecules formed at the surface of individual silver nanoparticles. By isolating a single nanoparticle on which the chemical reactions progress, the researchers can use a highly focused laser to excite molecules forming on the catalyst surface to create a spectral signal that identifies the molecules formed in discrete, elementary steps of the overall chemical process.

“I like to think of this work in terms of a story,” Jain said. “There is an overall theme to a story, which is the reduction of CO₂. The main characters are CO₂, H2O, silver nanoparticles, carbon monoxide and hydrogen ions, for example. But there are also some more minor but very interesting characters like butanol, acetate and oxalic acid that help tell the back story of the main characters. And sometimes, the minor characters are a lot more interesting than the major ones.”

Sometimes minor characters can come with some unintended players, Jain noted. To ensure that the intermediate carbon-based molecules the researchers detected are a result of the CO₂ reduction process and not contamination, they used CO₂ containing only carbon-13 isotope, which makes up only 1.1% of the carbon on Earth.

“Using carbon-13 to trace the reaction pathways allowed us to confirm that any hydrocarbons measured were there as a result of the CO₂ we intentionally added in the reaction vessel, and not accidentally introduced via contamination of the silver nanoparticles or later during the analysis process,” Jain said. “Carbon-13 is rare, so if we were to detect it in our reaction products, we would know it was the result of the light-driven conversion of CO₂ and C-C bond formation.”

The scale of multicarbon molecule formation by using silver nanoparticle catalysts remains very small at this stage of the research, Jain said. However, researchers can concentrate on developing improved synthetic catalysts and scaling up for industrial production, now that the promise of light-harvesting nanoparticles has been revealed.

One might want to know soon how much area is needed to produce a quantity of a few different hydrocarbons. But, for now it’s to soon to ask. There are sure to be some very interested parties following this. There is also a high probability that other drivers than light are going to be looked at as well. For those concerned about the fossil hydrocarbons running out, that concern is dwindling down with this kind of news.

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