An Extract Of Tumeric Found To Improve Ethanol Fuel Cells

Clemson University researchers have discovered a novel way to combine curcumin, the substance of interest in turmeric, and gold nanoparticles to create an electrode that requires 100 times less energy to efficiently convert ethanol into electricity.

In a surprise innovation, turmeric, a spice found in most kitchens, has an extract that could lead to safer, more efficient fuel cells.

In a collaboration the researchers at the Clemson Nanomaterials Institute (CNI) and their collaborators from the Sri Sathya Sai Institute of Higher Learning (SSSIHL) in India discovered the novel way to combine curcumin with gold nanoparticles.

The journal Nano Energy published the findings in a paper titled, “Green synthesis of a novel porous gold-curcumin nanocomposite for super-efficient alcohol oxidation.”

While the research team must do more testing, the discovery brings replacing hydrogen as a fuel cell feedstock one step closer.

Apparao Rao, CNI’s founding director and the R. A. Bowen Professor of Physics in the College of Science’s said, “Of all the catalysts for alcohol oxidation in alkaline medium, the one we prepared is the best so far.”

Fuel cells generate electricity through a chemical reaction instead of combustion. They are used to power vehicles, buildings, portable electronic devices and backup power systems.

Hydrogen fuel cells are highly efficient and do not produce greenhouse gases. While hydrogen is the most common chemical element in the universe, it must be derived from substances such as natural gas and fossil fuels because it occurs naturally on Earth only in compound form with other elements in liquids, gases or solids. The necessary extraction adds to hydrogen fuel cells’ cost and environmental impact.

In addition, hydrogen used in fuel cells is a compressed gas, creating difficult challenges for storage and transportation. Ethanol, an alcohol made from corn or other agricultural-based feedstocks, is safer and easier to transport than hydrogen because it is a liquid.

Lakshman Ventrapragada, a former student of Rao’s who worked as a research assistant at the CNI and is an alumnus of SSSIHL said, “To make it a commercial product where we can fill our tanks with ethanol, the electrodes have to be highly efficient. At the same time, we don’t want very expensive electrodes or synthetic polymeric substrates that are not eco-friendly because that defeats the whole purpose. We wanted to look at something green for the fuel cell generation process and making the fuel cell itself.”

The researchers focused on the fuel cell’s anode, where the ethanol or another feed source is oxidized.

Fuel cells widely use platinum as a catalyst. But platinum suffers from poisoning because of reaction intermediates such as carbon monoxide, Ventrapragada said. It is also very costly.

Ventrapragada designed the experiment during his thesis work in Rao’s CNI lab. The researchers used gold as a catalyst. Instead of using conducting polymers, metal-organic frameworks, or other complex materials to deposit the gold on the surface of the electrode, the researchers used curcumin because of its structural uniqueness. Curcumin is used to decorate the gold nanoparticles to stabilize them, forming a porous network around the nanoparticles. Researchers deposited the curcumin gold nanoparticle on the surface of the electrode at a 100 times lower electric current than in previous studies.

Ventrapragada noted that without the curcumin coating, the gold nanoparticles agglomerate, cutting down on the surface area exposed to the chemical reaction.

Rao explained, “Without this curcumin coating, the performance is poor. We need this coating to stabilize and create a porous environment around the nanoparticles, and then they do a super job with alcohol oxidation.

“There’s a big push in the industry for alcohol oxidation. This discovery is an excellent enabler for that. The next step is to scale the process up and work with an industrial collaborator who can actually make the fuel cells and build stacks of fuel cells for the real application,” he continued.

In addition the research could have broader implications than improved fuel cells. The electrode’s unique properties could lend itself to future applications in sensors, supercapacitors and more, Ventrapragada said.

In collaboration with the SSSIHL research team, Rao’s team is testing the electrode as a sensor that could help identify changes in the level of dopamine. Dopamine has been implicated in disorders such as Parkinson’s disease and attention deficit hyperactivity disorder. When members of the research team tested urine samples obtained from healthy volunteers, they could measure dopamine to the approved clinical range with this electrode using a cost-effective method compared to standard ones used today, Rao said.

“In the beginning stages of the project, we did not imagine other applications that gold-coated curcumin could support. However, before the end of the alcohol oxidation experiments, we were fairly confident that other applications are possible,” Ventrapragada said. “Although we don’t have a complete understanding of what’s happening at the atomic level, we know for sure that curcumin is stabilizing the gold nanoparticles in a way that it can lend itself to other applications.”

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On the face of the press release this all sounds just great. Your humble writer has a strong preference for fuel cells over batteries and light alcohols for hydrogen stabilization and storage. One hopes the press release means in stating “an electrode that requires 100 times less energy to efficiently convert ethanol into electricity” something well, understandable. One gets just a little lost with “100 times less”. Does that mean multiply by 0.01 for an answer? No one seems to know just what exactly is meant when using the phrase.

Meanwhile the abstract to the paper strongly suggests the “100 times less” energy thing might be in the creation of the catalyst.

While the press release is faithfully followed here and we’re near 60 days since asking the contact researcher about using the phrase, your humble writer is going ahead now with a lot less energy in the build of the catalyst and hopefully perhaps, a lot less activation energy to get a fuel cell up and running.

For now gold is less expensive than platinum and far more plentiful. More of it is in known deposits as well and its highly recyclable. A 20 gallon tank of ethanol fueling a highly efficient fuel cell could get an automobile a very long, safe and eco friendly way, indeed.

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