Copper Catalysts Make Carbon Dioxide To Methane Conversion

Rice University materials scientists developed copper-based catalysts to help speed up the rate of carbon dioxide-to-methane conversion. Technologies for removing carbon from the atmosphere keep improving, but solutions for what to do with the carbon once it’s captured are harder to come by.

The lab of Rice University materials scientist Pulickel Ajayan and collaborators developed a way to wrest the carbon from carbon dioxide and affix it to hydrogen atoms, forming methane – a valuable fuel and industrial feedstock.

According to the study published in Advanced Materials, the method relies on electrolysis and catalysts developed by grafting isolated copper atoms on two-dimensional polymer templates.

Soumyabrata Roy, a research scientist in the Ajayan lab and the study’s lead author explained, “Electricity-driven carbon dioxide conversion can produce a large array of industrial fuels and feedstocks via different pathways. However, carbon dioxide-to-methane conversion involves an eight-step pathway that raises significant challenges for selective and energy-efficient methane production. Overcoming such issues can help close the artificial carbon cycle at meaningful scales, and the development of efficient and affordable catalysts is a key step toward achieving this goal.”

The polymer templates, which were made of alternating carbon and nitrogen atoms, have tiny pores where copper atoms can fit at varying distances from one another. The catalysts assemble at room temperature in water with the copper atoms displacing the host metal ions in the polymer templates. When tested in a reactor, the catalysts enabled the reduction of carbon dioxide to methane in one half of the cell, while oxygen was produced from water in the other half.

Roy noted, “We found that modulating the distances between the copper atoms lowered the energy needed for key reaction steps, thereby speeding up the chemical conversion. This cooperative action of nearby copper atoms helped produce methane at a very high rate of selectivity and efficiency.”

The catalysts developed by Roy and collaborators yielded one of the most rapid and efficient electrolysis-based conversions of carbon dioxide to methane known so far, helping advance the conversion process both in terms of fundamental scientific insight and performance level.

Jingjie Wu, an associate professor of chemical and environmental engineering at the University of Cincinnati commented, “If system-level energy and carbon conversion efficiencies can be addressed, inexpensive and efficient materials like these will help catalyze the industrial translation of electrochemical carbon dioxide reduction technology,”

Ajayan, Rice’s Benjamin M. and Mary Greenwood Anderson Professor of Engineering and chair of the Department of Materials Science and NanoEngineering, added that the “design and development of novel catalysts are central to the energy and sustainability challenges we face. Single-atom dispersed catalysts present an exciting approach in this effort.”

Wu and Chandra Veer Singh, a professor of materials science and engineering at the University of Toronto, were key contributors to the study.

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This looks like a very smart alternative to trying to pump carbon dioxide deep into the ground. Although the tree lovers idea to give a tree a treat with some extra carbon dioxide hasn’t made headway with politicians and media types, the idea remains sound and quite attractive to the botanists’ community.

To put it simply, it would be good if humanity could use carbon resources in such a way that we stay current in the planetary carbon cycle i.e. we just keep the carbon dioxide level at a healthy level cycling for the plant and the animal kingdoms.

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