Solid State Electrolytes Bringing Revolution To Batteries

Researchers announced a major breakthrough in the field of next-generation solid-state chloride-based solid electrolyte batteries. It is believed that their new findings will enable the creation of batteries that exhibit exceptional ionic conductivity.

The researchers led by Professor Kisuk Kang of the Center for Nanoparticle Research within the Institute for Basic Science (IBS), announced the major breakthrough with a research paper published in the journal Science.

A pressing concern with current commercial batteries their reliance on liquid electrolytes, which leads to flammability and explosion risks. Therefore, the development of non-combustible solid electrolytes is of paramount importance for advancing solid-state battery technology.

As the world gears up to regulate internal combustion engine vehicles and expand the use of electric vehicles in the ongoing global shift toward sustainable transportation, research into the core components of secondary batteries, particularly solid-state batteries, has gained significant momentum.

To make solid-state batteries practical for everyday use, it is crucial to develop materials with high ionic conductivity, robust chemical and electrochemical stability, and mechanical flexibility. While previous research successfully led to sulfide and oxide-based solid electrolytes with high ionic conductivity, none of these materials fully met all these essential requirements.

To create a sufficiently wide pathway for lithium ions within each layer, the occupancy of metal ions should be more than 0.167. Therefore, achieving an occupancy of metal ions between 0.167 and 0.444 within each layer results in a conductive layer with high ionic conductivity. Image Credit: Institute for Basic Science.

In the past, scientists have also explored chloride-based solid electrolytes, known for their superior ionic conductivity, mechanical flexibility, and stability at high voltages. These properties led some to speculate that chloride-based batteries are the most likely candidates for solid-state batteries. However, these hopes quickly died out, as the chloride batteries were considered impractical due to their heavy reliance on expensive rare earth metals, including yttrium, scandium, and lanthanide elements, as secondary components.

To address these concerns, the IBS research team looked at the distribution of metal ions in chloride electrolytes. They believed the reason trigonal chloride electrolytes can achieve low ionic conductivity is based on the variation of metal ion arrangements within the structure.

They first tested this theory on lithium yttrium chloride, a common lithium metal chloride compound. When the metal ions were positioned near the pathway of lithium ions, electrostatic forces caused obstruction in their movement. Conversely, if the metal ion occupancy was too low, the path for lithium ions became too narrow, impeding their mobility.

Building on these insights, the research team introduced strategies to design electrolytes in a way that mitigates these conflicting factors, ultimately leading to the successful development of a solid electrolyte with high ionic conductivity.

The group went further to successfully demonstrate this strategy by creating a lithium-metal-chloride solid-state battery based on zirconium, which is far cheaper than the variants that employ rare earth metals. This was the first instance where the significance of the metal ions arrangement on a material’s ionic conductivity was demonstrated.

This research brings to light the often-overlooked role of metal ion distribution in the ionic conductivity of chloride-based solid electrolytes. It is expected that the IBS Center’s research will pave the way for the development of various chloride-based solid electrolytes and further drive the commercialization of solid-state batteries, promising improved affordability and safety in energy storage.

Corresponding author Kisuk Kang stated, “This newly discovered chloride-based solid electrolyte is poised to transcend the limitations of conventional sulfide and oxide-based solid electrolytes, bringing us one step closer to the widespread adoption of solid-state batteries.”

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It is great to see this level of improvement appear for batteries. The day is coming that has battery power storage as a common satisfying attribute.

What’s not covered is the absence (for the U.S, in particular) of generating capacity to charge the proposed fleets of battery energized products. Then there is the matter of a grid with enough capacity to deliver all that power. The media remains strangely silent, inviting mass ignorance.

It would be good for funding to get behind this tech and discover the real world advantages and shortcomings early on.

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